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The NMR spectra and conformations of cyclic compounds–III: The conformations of some pinane derivatives

 

作者: R. J. Abraham,   F. H. Bottom,   M. A. Cooper,   J. R. Salmon,   D. Whittaker,  

 

期刊: Organic Magnetic Resonance  (WILEY Available online 1969)
卷期: Volume 1, issue 1  

页码: 51-56

 

ISSN:0030-4921

 

年代: 1969

 

DOI:10.1002/mrc.1270010108

 

出版商: John Wiley&Sons Limited

 

数据来源: WILEY

 

摘要:

AbstractThe 220 MHz1H spectra of isoverbanone, nopinone and verbanone are reported.The spectra of the first two are completely assigned but that of verbanone only partially. The coupling constants obtained provide information about the conformation of these molecules. The isoverbanone molecule is almost Y shaped, but that of nopinone is between a Y shape and a half‐chair conformation with the six membered ring bent away form the gem dimethyl groups. These conformations are consistent with the known steric interactions in these molecule

 

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