The Fundamental Basis for Cyclopolymerization. II. The Relation of In-Plane-Deformation Vibrations of Terminal Methylene Groups of 1,6-Heptadienes to Polymerizability
作者:
GeorgeB. Butler,
W.Lamar Miller,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1969)
卷期:
Volume 3,
issue 8
页码: 1493-1507
ISSN:0022-233X
年代: 1969
DOI:10.1080/10601326908051948
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A number of 4-substituted 1,6-heptadienes have been prepared and their infrared absorption characteristics compared with their polymerizability. This group of compounds included several N,N-diallylamides, diallylcyanamide, diallyl-(tricyanovinyl)-amine, diallylammonium bromide, diallylmethylphosphine oxide, diallylphenylphosphine oxide, diallylmethylphenylphosphonium bromide, and dimethyl-4-penteneamine. The frequencies of the in-plane-deformation vibration of the terminal methylene groups varied from 1411 to 1437 cm−1. The higher frequencies were attributed to the electron withdrawal effect of the substituent in the 4 position. Those compounds having higher absorption frequencies also undergo polymerization more readily than those in the lower-frequency range. These correlations are presented as substantiating evidence for an intramolecular interaction in the monomers which can in part explain the facile but highly improbable cyclopolymerization mechanism.
点击下载:
PDF (532KB)
返 回