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On the Evaluation of Chemical Relaxation Measurements with Sampling Technique and On-Line Processing

 

作者: M. Križan,   H. Strehlow,  

 

期刊: Instrumentation Science & Technology  (Taylor Available online 1974)
卷期: Volume 5, issue 2  

页码: 99-108

 

ISSN:1073-9149

 

年代: 1974

 

DOI:10.1080/10739147408543362

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A relatively simple digitizing interface for use in chemical relaxation experiments is described. It is possible to sample by repeating the experiments and adding the data in a small on-line computer. This technique has considerably improved the accuracy obtainable in relaxation experiments as well as the speed of data acquisition. The relaxation data, which are corrected by the computer program for superimposed exponential decay processes of small amplitude, are available immediately after the experiment. By integrating the analog signal before digitization, nearly optimal electronic filtering is achieved. The technique has been extensively used in the pressure-jump technique but is applicable also to related methods. An example for the application to signals which do not change exponentially with time illustrates further possibilities of the proposed technique.

 

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