An improved understanding of efficiency limiting defects in polycrystalline CdTe/CdS solar cells
作者:
A. Rohatgi,
H. C. Chou,
A. Bhat,
R. Sudharsanan,
期刊:
AIP Conference Proceedings
(AIP Available online 1992)
卷期:
Volume 268,
issue 1
页码: 243-249
ISSN:0094-243X
年代: 1992
DOI:10.1063/1.42920
出版商: AIP
数据来源: AIP
摘要:
Efficiency limiting mechanisms in CdTe/CdS solar cells were investigated. It was found that growth of CdTe films under tellurium rich conditions enhanced the interdiffusion between CdTe and CdS and reduced the CdTe bandgap to 1.47 eV, whereas, growth of CdTe films under Cd‐rich conditions retained the CdTe bandgap at 1.5 eV. A CdCl2treatment followed by a 400 °C post‐growth annealing of CdTe improved the cell performance significantly. However, it also produced defects atEv+0.64 andEv+0.17 eV possibly due to chlorine related complexes. An inverse correlation was found between the density of these defects andVoc. Rapid thermal processing (RTP) was investigated as a variation of the conventional furnace anneal post‐growth treatment. Preliminary RTP results look promising with cell efficiency in excess of 8% without any CdCl2treatment. Further improvements are expected by optimizing the CdCl2treatment and the RTP conditions.
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