Vinyl esters of 4‐aroyl butyric acids and their polymers
作者:
Heinrich Hopff,
Maged A. Osmaw,
期刊:
Die Angewandte Makromolekulare Chemie
(WILEY Available online 1969)
卷期:
Volume 6,
issue 1
页码: 39-45
ISSN:0003-3146
年代: 1969
DOI:10.1002/apmc.1969.050060103
出版商: Hüthig&Wepf Verlag
数据来源: WILEY
摘要:
AbstractVinyl 4‐benzoyl butyrate, vinyl 4‐(p‐toluoyl) butyrate and vinyl 4‐(m‐nitro‐benzoyl) butyrate were prepared by vinyl interchange with vinyl acetate. Theoptimum conditions for the preparation of these monomers have been studied.Their structures were established by NMR spectroscopy. The polymers of thesemono em were synthesised by free radical polymerization, their molecular weightsand glass temperatures determined. Vinyl 4‐(m‐nitrobenzoyl) butyrate was not‐polymerizable. Vinyl 4‐benzoyl butyrate showed degradcttive transfer reaction on polymerization due to the presence of acti
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