Non‐Enzymatic Synthesis of Polysaccharides, Nucleosides and Nucleic Acids and the Origin of Self‐Reproducing Systems
作者:
G. Schramm,
H. Grötsch,
W. Pollmann,
期刊:
Angewandte Chemie International Edition in English
(WILEY Available online 1962)
卷期:
Volume 1,
issue 1
页码: 1-7
ISSN:0570-0833
年代: 1962
DOI:10.1002/anie.196200011
出版商: Hüthig&Wepf Verlag
关键词: Polysaccharides;Nucleosides;Nucleic acids;DNA replication
数据来源: WILEY
摘要:
AbstractCompounds containing free amino, hydroxyl or carbonyl groups can be activated by reaction with polyphosphate ester. If the compounds contain a second functional group, polycondensations are possible; e.g. amino acids → polypeptides, carbohydrates → polysaccharides, nucleotides → polynucleotides. In the presence of polyadenylic acid, polymerization of uridylic acid is speeded up tenfold. This mutual effect of complementary nucleotide strands constitutes the experimental basis for a hypothesis concerning the terrestrial origin of systems capable of self‐repro
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