Raman Scattering of H2O/D2O Solutions
作者:
I. Savatinova,
E. Anachkova,
R. Nikolaeva,
期刊:
Spectroscopy Letters
(Taylor Available online 1986)
卷期:
Volume 19,
issue 2
页码: 167-178
ISSN:0038-7010
年代: 1986
DOI:10.1080/00387018608069229
出版商: Taylor & Francis Group
关键词: stretching vibrations;H-bond;isotopic dilution
数据来源: Taylor
摘要:
The stretching vibrations of water are perfect characteristics of the hydrogen bond. Studying their frequency shift, changes of intensities, broadening of the bands and appearence of submaxima we can receive very important structural information about the groups involved in H-bonding and about the bond itself. The observed Raman spectra, however, are rather complicated because the OH and OD stretching bands are always superpositions of several bands due to intra- and intermolecular coupling, effect of Fermi resonance etc. The
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