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&bgr;‐relaxation near glass transitions

 

作者: L. Sjo¨gren,   W. Go¨tze,  

 

期刊: AIP Conference Proceedings  (AIP Available online 1992)
卷期: Volume 256, issue 1  

页码: 105-114

 

ISSN:0094-243X

 

年代: 1992

 

DOI:10.1063/1.42447

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The relaxation properties of the &bgr;‐process as described within the mode‐coupling theory for the dynamics of supercooled liquids is reviewed. This process is completely ruled by generic properties of underlying bifurcation singularities in the nonlinear equations of motion. The singularities belong to the cuspoid familyAkwithk≥2, and lead to various scaling scenarios involving one or more parameter scaling functions depending on the orderkof the relevant singularity. The theoretical predictions are compared with dielectric measurements on several polymeric systems, and in the relevant frequency region we find a quantitative agreement between theory and experimental results.

 

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