Design of Novel Chalcogen-Containing Organic Metals: Extensively Conjugated Electron Donors and Acceptors With Reduced On-Site Coulomb Repulsion
作者:
Fumio Ogura,
Tetsuo Otsubo,
Yoshio Aso,
期刊:
Sulfur reports
(Taylor Available online 1992)
卷期:
Volume 11,
issue 3
页码: 439-464
ISSN:0196-1772
年代: 1992
DOI:10.1080/01961779208048774
出版商: Taylor & Francis Group
关键词: Conductive charge-transfer complexes;conjugated electron donors and acceptors;design of organic metals;effect of heteroatoms;hetero-TCNQ;reduced on-site Coulomb repulsion
数据来源: Taylor
摘要:
This review describes the design of extensively conjugated electron donors and acceptors based on structural modifications of tetrathiafulvalene (TTF) and tetracyanoquinodimethane (TCNQ), respectively. These molecules have the advantage of reduced on-site Coulomb repulsion which is one of the prerequisites for components of organic metals. The construction of such large compounds is currently accomplished by insertion of an extensively π-conjugated system between two 1,3-dithiolylidene or dicyanomethylene groups. The usefulness of a heteroquinoid system as such a building block is demonstrated by examples of heteroatom-incorporating TCNQ acceptors (hetero-TCNQs), which form a variety of highly conductive charge-transfer complexes. In addition, recent advances concerning quino-2,2′-bis(1,3-dithioles) and TTF vinylogs as novel electron donors are introduced.
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