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Transport properties in ordinary and supercooled liquids

 

作者: U. Balucani,   S. F. Duffy,   A. Torcini,   R. Vallauri,  

 

期刊: AIP Conference Proceedings  (AIP Available online 1992)
卷期: Volume 256, issue 1  

页码: 126-129

 

ISSN:0094-243X

 

年代: 1992

 

DOI:10.1063/1.42450

 

出版商: AIP

 

数据来源: AIP

 

摘要:

A satisfactory microscopic theory of transport coefficients in dense fluids requires the consideration both of fast collisional events and of much slower decay mechanisms. In general, such approaches are necessarily complicated; fortunately, in ordinary and moderately supercooled liquids several physical approximations can be made to yield a considerably simpler analysis. This framework has been successfully applied to evaluate the diffusion and shear viscosity coefficients in several typical simple liquids. Further simplications are possible in the case of the diffusion coefficient, which can be expressed analytically. The practical advantages of this approach are illustrated for liquid Cs, obtaining results in good agreement with the observed data.

 

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