Gas Chromatographic Separation of Halocarbons on Porapak Q Porous Polymer Beads
作者:
A. Foris,
J.G. Lehman,
期刊:
Separation Science
(Taylor Available online 1969)
卷期:
Volume 4,
issue 3
页码: 225-241
ISSN:0037-2366
年代: 1969
DOI:10.1080/01496396908052254
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Kováts retention indices can be used to characterize the gas chromatographic behavior of C1and C2halocarbons on Porapak Q. Within each series of halocarbons the retention index increases with chlorine content, decreases with fluorine and hydrogen content, and is directly proportional to molecular weight and boiling point. Substitution of a fluorine or a bromine atom for a chlorine atom in these compounds results in characteristic changes in the retention index. The heats of adsorption are in the neighborhood of the latent heats of vaporization for the compounds examined.
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