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MS/MS of energetic compounds. A collisional induced dissociation study of some polynttrobishcmocubanes

 

作者: Jehuda Yinon,   Suryanarayana Bulusu,  

 

期刊: Journal of Energetic Materials  （Taylor Available online 1986）
卷期: Volume 4, issue 1-4  

页码: 115-131

 

ISSN:0737-0652

 

年代: 1986

 

DOI:10.1080/07370658608011336

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A collisional induced dissociation (CID) study was done on 3,5,5-trinitropentacyclodecane and 5,5-dinitropentacyclodecane-3-carboxylic acid using tandem high-resolution MS/MS. Fragmentation pathways were determined in the El ionization mode. It was found that fragmentation of the C-N bonds–resulting in losses of the NO2groups–takes place before the fragmentation of the C-C bonds.

 

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