Esr Studies of Some Crowded Free Radicals Derived from Oxalate Esters
作者:
Siddik Içli,
Faruk Güler,
期刊:
Spectroscopy Letters
(Taylor Available online 1984)
卷期:
Volume 17,
issue 12
页码: 775-781
ISSN:0038-7010
年代: 1984
DOI:10.1080/00387018408075705
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The temperature independent esr spectrum of di-i-Propyl-t-butylmethyl radical, derived from photolysis of oxalate ester, indicates a frozen “cogwhell” conformation for this specie. The neo-pentyl substituted oxalate esters are suggested to qive β-hydrogen abstraction on presence of di-t-butylperoxide on photolysis.
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