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Hardness of Crystals with NaCl Structure and the Significance of the GILMAN‐CHIN Parameter

 

作者: D. B. Sirdeshmukh,   K. G. Subhadra,   K. Kishan Rao,   T. Thirmal Rao,  

 

期刊: Crystal Research and Technology  (WILEY Available online 1995)
卷期: Volume 30, issue 6  

页码: 861-866

 

ISSN:0232-1300

 

年代: 1995

 

DOI:10.1002/crat.2170300625

 

出版商: WILEY‐VCH Verlag

 

数据来源: WILEY

 

摘要:

AbstractThe microhardness of PbTe, PbSe, EuS and EuSe has been determined. The microhardness vs lattice constant plot for chalcogenides is a curve similar to the one for alkali halides. The Gilman‐Chin parameter (H/C44) has been calculated for a large number of crytals with NaCl structure. There is no unique value representing the entire group of crystals, the values ranging from 0.01 to 0.20.The Gilman‐Chin parameter broadly correlates with the effective ionic charge (e) indicating that it is a measure of the ionicity. Empirically, it is observed that the product (H/C44) · (e)2is approximately cons

 

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