A computational study of physical and chemical inhibition in a perfectly stirred reactor
作者:
Nancy J. Brown,
Robert W. Schefer,
期刊:
Fire and Materials
(WILEY Available online 1981)
卷期:
Volume 5,
issue 1
页码: 14-23
ISSN:0308-0501
年代: 1981
DOI:10.1002/fam.810050104
出版商: Heyden&Son Ltd.
数据来源: WILEY
摘要:
AbstractThis paper reports a set of modeling studies that were undertaken to acquire a more detailed knowledge of combustion inhibition mechanisms. Mixtures of H2/O2/Ar reacting in the idealized perfectly stirred reactor were investigated. Three H2/O2kinetic mechanisms were considered, differing from one another by the number of HO2reactions included. Two physical inhibitors, Ar and N2, and one chemical inhibitor, HBr, were investigated. Additional parameters considered were pressure, equivalence ratio, inhibitor concentration and rate coefficient variation. The most effective inhibitor was HBr which acted chemically and caused substantial reduction in radical concentrations in the mixtures considered. The molecules Ar and N2acted as physical diluents with N2, the more effective of the two due to its larger heat capacity.
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