首页   按字顺浏览 期刊浏览 卷期浏览 Molecular hyperpolarizabilities determined from conjugated and nonconjugated organic li...
Molecular hyperpolarizabilities determined from conjugated and nonconjugated organic liquids

 

作者: B. F. Levine,   C. G. Bethea,  

 

期刊: Applied Physics Letters  (AIP Available online 1974)
卷期: Volume 24, issue 9  

页码: 445-447

 

ISSN:0003-6951

 

年代: 1974

 

DOI:10.1063/1.1655254

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The magnitude and sign (positive) of the molecular hyperpolarizability &ggr; has been determined for several mixtures of nitrobenzene and benzene. This has allowed the testing of the adequacy of Onsager's local field factors, which are found to be valid. By comparing &ggr; of nitrobenzene with that of nitromethane, we find that the delocalized conjugated electrons are an order of magnitude more effective in contributing to &ggr; than are the localized nonconjugated electrons.

 

点击下载:  PDF (258KB)



返 回