Molecular hyperpolarizabilities determined from conjugated and nonconjugated organic liquids
作者:
B. F. Levine,
C. G. Bethea,
期刊:
Applied Physics Letters
(AIP Available online 1974)
卷期:
Volume 24,
issue 9
页码: 445-447
ISSN:0003-6951
年代: 1974
DOI:10.1063/1.1655254
出版商: AIP
数据来源: AIP
摘要:
The magnitude and sign (positive) of the molecular hyperpolarizability &ggr; has been determined for several mixtures of nitrobenzene and benzene. This has allowed the testing of the adequacy of Onsager's local field factors, which are found to be valid. By comparing &ggr; of nitrobenzene with that of nitromethane, we find that the delocalized conjugated electrons are an order of magnitude more effective in contributing to &ggr; than are the localized nonconjugated electrons.
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