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Examination of the RatioDv/Hvfor Infrared Bands Assigned to the C-H(D) and Ring Vibrations in Metal Complexes of Quinoline, Pyridine, Aniline and Their Fully-Deuterated Analogues

 

作者: G.A. Foulds,   J.B. Hodgson,   A.T. Hutton,   M.L. Niven,   G.C. Percy,   P.E. Rutherford,   D.A. Thornton,  

 

期刊: Spectroscopy Letters  （Taylor Available online 1979）
卷期: Volume 12, issue 1  

页码: 25-32

 

ISSN:0038-7010

 

年代: 1979

 

DOI:10.1080/00387017908063476

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The infrared spectra of sixteen metal complexes comprising the ligands quinoline, pyridine, aniline and their fully-deuterated analogues have been examined in order to determine the ratioDv/Hvfor bands assigned to the C-H and ring modes of the heterocyclic or aromatic ring. With very few exceptions,Dv/Hvfalls within the ranges 0.68 to 0.85 for C-H vibrations and 0.85 to 1.00 for ring modes. The ranges are narrower for complexes of a specific amine. The potential usefulness of the results is discussed.

 

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