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Stress relaxation in heterogeneous polymers

 

作者: T. A. Witten,  

 

期刊: AIP Conference Proceedings  (AIP Available online 1992)
卷期: Volume 256, issue 1  

页码: 245-252

 

ISSN:0094-243X

 

年代: 1992

 

DOI:10.1063/1.42358

 

出版商: AIP

 

数据来源: AIP

 

摘要:

When heterogeneous polymers such as diblock copolymers form a microdomain phase, an imposed strain gives rise to stress from two sources, and several mechanisms of stress relaxation. The release of stress by disentanglement is strongly influenced by the effective confinement of the junction points to the domain boundaries and by the stretching of the chains. Using accepted notions of entangled chain kinetics, it is argued that the relaxation time for sliding stress is exponential in the chainlength to the 7/9 power. A method for calculating the frequency‐dependent dynamic modulus is sketched. Despite the slow relaxation implied by these mechanisms, it appears possible to create domains of high energy.

 

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