The Fundamental Basis for Cyclopolymerization. I. Unconjugated Chromophoric Interactions Related to Cyclopolymerization
作者:
GeorgeB. Butler,
Bruno Iachia,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1969)
卷期:
Volume 3,
issue 5
页码: 803-819
ISSN:0022-233X
年代: 1969
DOI:10.1080/10601326908051916
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A far ultraviolet study showed progressive bathochromic wavelength shifts within the following series of compounds: (i) allyltrimethylsilane, diallyldimethylsilane, triallylmethylsilane, tetraallylsilane; (ii) allyltripropylsilane, diallyldipropylsilane, triallylpropylsilane; (iii) 4,4-dimethyl-1-pentene, 4,4-dimethyl-1,6-heptadiene, 4-allyl-4-methyl-1,6-heptadiene. In the series tri-methylvinylsilane, dimethyldivinylsilane, methyltrivinylsilane, and tetravinylsilane, trimethylvinylsilane was shifted bathochromically from the rest of the vinylsilanes, which were grouped together. Allyldimethylvinylsilane showed two independent absorptions.
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