Vinyl chloride studies. II. Initiation and termination in the homogeneous polymerization of vinyl chloride
作者:
Geoffrey S. Park,
Dennis G. Smith,
期刊:
Die Makromolekulare Chemie
(WILEY Available online 1970)
卷期:
Volume 131,
issue 1
页码: 1-6
ISSN:0025-116X
年代: 1970
DOI:10.1002/macp.1970.021310101
出版商: Hüthig&Wepf Verlag
数据来源: WILEY
摘要:
AbstractThe polymerization of 4 and 5 molar vinyl chloride in chlorobenzene solution has been studied using 0.005 to 0.1 molar14C labelled azoisobutyronitrile as initiator at temperatures of 30 and 40°C. The number of initiator fragments per polymer molecule increases with the rate of initiation and extrapolates to 1.15 at an infinite rate of initiation showing that 25% of mutual termination occurs by combination and 75% by disproportionation. Values found for the efficiency of initiation vary from about 70% at the lowest initiator concentration to 55% at the highest
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