Raman Spectra of Pyridine Adsorbed on Supported Molybdate Catalysts
作者:
C.P. Cheng,
G.L. Schrader,
期刊:
Spectroscopy Letters
(Taylor Available online 1979)
卷期:
Volume 12,
issue 11-12
页码: 857-870
ISSN:0038-7010
年代: 1979
DOI:10.1080/00387017908069210
出版商: Taylor & Francis Group
关键词: Adsorbed species;molybdate catalysts
数据来源: Taylor
摘要:
Pyridine adsorption was used as a probe of the surface structure of supported molybdate and cobalt molybdate catalysts. The catalysts consisted of a γ-Al2O3support which had been impregnated with various molybdenum loadings ranging from 1.25% to 15% (MoO3). The Raman spectra of the catalyst and of the adsorbed pyridine indicated that a considerable portion of the alumina surface was not covered by molybdenum even after molybdenum trioxide was formed. Brnsted acid site and Lewis acid site adsorption were observed for low
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