Vibrational Behaviour of the CrO3-4Anion in Different Crystalline Environments
作者:
EnriqueJ. Baran,
SilviaG. Manca,
期刊:
Spectroscopy Letters
(Taylor Available online 1984)
卷期:
Volume 17,
issue 12
页码: 827-837
ISSN:0038-7010
年代: 1984
DOI:10.1080/00387018408075709
出版商: Taylor & Francis Group
关键词: IR-spectra;Raman spectra;site-symmetry effects;force constants;bond properties
数据来源: Taylor
摘要:
The powder-infrared spectra of different crystalline compounds containing the tetrahedral Cro3-4, anion have been recorded and analyzed with the aid of the site symmetry rules. In some cases Raman data are also reported. The effect of the different crystalline environments is discussed in detail and comparisons with isostructural phases are also made. A definitive assignment for the internal vibrations of the CrO3-4, ion is proposed and a new set of force constants has been calculated fron a modified valence force field.
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