Spectrophotometric Determination of Silver (I) Using 3-Methyl-1, 2-Cyclopentanodione Dithiosemicarbazone
作者:
Radi Salim,
A.H. Laila,
期刊:
Spectroscopy Letters
(Taylor Available online 1985)
卷期:
Volume 18,
issue 8
页码: 593-600
ISSN:0038-7010
年代: 1985
DOI:10.1080/00387018508076914
出版商: Taylor & Francis Group
关键词: Spectrophotometry;Silver Determination;3-Me-CPDT;Complex Properties
数据来源: Taylor
摘要:
The complex of silver (I) with the reagent 3-methyl-1, 2-cyclopentanodione dithiosemicarbazone, 3-Me-CPDT, has been studied spectrophotometrically. Few properties of the complex such as its composition, stability, and free energy of formation have been determined. A sensitive method of analysis for silver in aqueous solutions has been developed based on the spectrophotometric measurement of the absorption of the Ag-3-Me-CPDT complex. The optimum conditions for applying this method for the determination of Ag(I) have been determined. These conditions include the standing time, pH, wavelength, and the effect of interfering ions.
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