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A New Approach to (−)-Anisomycin

 

作者: PeiQiang Huang,   ShiLi Wang,   YuanPing Ruan,   JingXing Gao,  

 

期刊: Natural Product Letters  （Taylor Available online 1998）
卷期: Volume 11, issue 2  

页码: 101-106

 

ISSN:1057-5634

 

年代: 1998

 

DOI:10.1080/10575639808041204

 

出版商: Taylor & Francis Group

 

关键词: Anisomycin;Malic Acid;Reductive alkylation;Asymmetric Synthesis

 

数据来源: Taylor

 

摘要:

(R)-(−)-1-Benzyloxycarbonyl-2-(4-methoxyphenyl)methyl-3-pyrroline (16) was prepared from (S)-malic acid. The key steps involved a highly regio andtransstereoselective reductive alkylation of N-benzylmalimide (4). This constitutes a formal asymmetric synthesis of natural (-)-anisomycin (2).

 

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