Nonequilibrium Flow and the Kinetics of Chemical Reactions in the Char Zone
作者:
GaryC. April,
RalphW. Pike,
EduardoG. Del Valle,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1969)
卷期:
Volume 3,
issue 4
页码: 685-704
ISSN:0022-233X
年代: 1969
DOI:10.1080/10601326908053836
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
In the temperature range of 500–2500°F, nonequilibrium flow analysis predicted only a small change in pyrolysis gas composition as the gases flow through the char zone. Essentially all of the reactions took place in the temperature range of 2000–2500°F. Comparing nonequilibrium flow with the two limiting cases, the energy absorbed in the char zone for frozen flow was two-thirds that of nonequilibrium flow, and equilibrium flow was about four times that of nonequilibrium flow at the 2500°F level.
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