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Nonequilibrium Flow and the Kinetics of Chemical Reactions in the Char Zone

 

作者: GaryC. April,   RalphW. Pike,   EduardoG. Del Valle,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1969)
卷期: Volume 3, issue 4  

页码: 685-704

 

ISSN:0022-233X

 

年代: 1969

 

DOI:10.1080/10601326908053836

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

In the temperature range of 500–2500°F, nonequilibrium flow analysis predicted only a small change in pyrolysis gas composition as the gases flow through the char zone. Essentially all of the reactions took place in the temperature range of 2000–2500°F. Comparing nonequilibrium flow with the two limiting cases, the energy absorbed in the char zone for frozen flow was two-thirds that of nonequilibrium flow, and equilibrium flow was about four times that of nonequilibrium flow at the 2500°F level.

 

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