A Study of Retention in Thermal Field-Flow Fractionation
作者:
MarcusN. Myers,
KarinD. Caldwell,
J.Calvin Giddings,
期刊:
Separation Science
(Taylor Available online 1974)
卷期:
Volume 9,
issue 1
页码: 47-70
ISSN:0037-2366
年代: 1974
DOI:10.1080/01496397408080043
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A broad theoretical and experimental investigation of retention in thermal field-flow fractionation is reported here. Equations connecting retention parameters with underlying thermal diffusion constants are reviewed, and new equations are developed to account for the distortion of the flow profile caused by a variable viscosity. Parameters investigated experimentally include channel width, solute molecular weight, channel temperature drop, cold-wall temperature, sample size, and solvent effects. All but the last two of these experimental studies showed good conformity with theoretical predictions. No theory exists for the prediction of sample-size or solvent effects. With regard to the latter, experimental results show that a variety of organic solvents are very effective, at roughly equal levels, in providing retention, while aqueous solvents are generally ineffective.
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