首页   按字顺浏览 期刊浏览 卷期浏览 A Study of Retention in Thermal Field-Flow Fractionation
A Study of Retention in Thermal Field-Flow Fractionation

 

作者: MarcusN. Myers,   KarinD. Caldwell,   J.Calvin Giddings,  

 

期刊: Separation Science  (Taylor Available online 1974)
卷期: Volume 9, issue 1  

页码: 47-70

 

ISSN:0037-2366

 

年代: 1974

 

DOI:10.1080/01496397408080043

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A broad theoretical and experimental investigation of retention in thermal field-flow fractionation is reported here. Equations connecting retention parameters with underlying thermal diffusion constants are reviewed, and new equations are developed to account for the distortion of the flow profile caused by a variable viscosity. Parameters investigated experimentally include channel width, solute molecular weight, channel temperature drop, cold-wall temperature, sample size, and solvent effects. All but the last two of these experimental studies showed good conformity with theoretical predictions. No theory exists for the prediction of sample-size or solvent effects. With regard to the latter, experimental results show that a variety of organic solvents are very effective, at roughly equal levels, in providing retention, while aqueous solvents are generally ineffective.

 

点击下载:  PDF (925KB)



返 回