This review examines the importance of the thermal boundary layer of the ocean to the measurement of sea surface temperature (SST) by satcllitc-bornc infrared (IR) radiometers. Attention is focused on the difference between the temperature of the top 01mm which is observed by radiometers, and the temperature found at depths between a few centimetres and one metre, which is that recorded as bulk SST by ship measurement techniques. The question addressed is whether corrections for this effect are necessary in the light of the accuracy of IR radiometers, and the demands made by the application of SST data.