Effect of Di-t-Butyl Peroxide on the Lean Operating Limit of a Spark-Ignition Engine
作者:
STEPHENJ. HARRIS,
BRUCED. PETERS,
期刊:
Combustion Science and Technology
(Taylor Available online 1982)
卷期:
Volume 29,
issue 3-6
页码: 293-298
ISSN:0010-2202
年代: 1982
DOI:10.1080/00102208208923604
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A study was conducted to determine whether the addition of di-t-butyl peroxide to unleaded gasoline would extend the lean operating limit of a spark-ignition engine. Tests were conducted with a single-cylinder, Cooperative Fuel Research engine. In these tests, the lean misfire limit equivalence ratio was extended by 6 and 10 percent with blends of 1 and 5 volume percent, respectively, of di-t-butyl peroxide and unleaded gasoline, compared to the value obtained with only unleaded-gasoline. It is hypothesized that the improved lean combustion was caused by the dissociation of di-t-butyl peroxide to tertiary butoxy radicals, which in turn reacted with the unleaded gasoline thus increasing the fuel oxidation rate.
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