Angular Dependent57Fe Moessbauer Measurements of Oriented Mica
作者:
M. Krause,
C. Michalk,
G. Just,
期刊:
Isotopenpraxis Isotopes in Environmental and Health Studies
(Taylor Available online 1987)
卷期:
Volume 23,
issue 5
页码: 173-177
ISSN:0021-1915
年代: 1987
DOI:10.1080/10256018708623786
出版商: Taylor & Francis Group
关键词: iron 57;mica;moessbauer effect;quadrupoles;structural chemical analysis;texture
数据来源: Taylor
摘要:
In the Moessbauer spectra of several mica we find asymmetric quadrupole doublets. In the case of perpendicular γ-ray propagation the asymmetry is the greatest, and it vanishes, if the angle between surface normal direction and γ-ray direction is equal to the magic angle (54.7°). In all substances the quadrupole splitting of the Fe2+ions is negative and those of the Fe3+ions positive. The angular dependence of the spectra is in a good agreement with the picture of an axial symmetric EFG-texture distribution.
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