首页   按字顺浏览 期刊浏览 卷期浏览 An Electrochemical Flow Cell For The Detection Of Metal Complexes
An Electrochemical Flow Cell For The Detection Of Metal Complexes

 

作者: StevenA. Cohen,   DuaneE. Bartak,  

 

期刊: Analytical Letters  (Taylor Available online 1983)
卷期: Volume 16, issue 6  

页码: 429-441

 

ISSN:0003-2719

 

年代: 1983

 

DOI:10.1080/00032718308065179

 

出版商: Taylor & Francis Group

 

关键词: Flow Cell;Reticulated Vitreous Carbon Electrode;Metal Complex Separation;Modified Gel Permeation Chromatography

 

数据来源: Taylor

 

摘要:

An electrochemical flow cell has been developed using reticulated vitreous carbon (RVC) coated with a thin film of mercury. The flow cell and electrode components are inexpensive and easily constructed. Reproducible results have been obtained for concentrations as low as 100 ppb. Peak currents were dependent on flow rate, electrode size, and mercury deposition time. Oxygen interference was reduced by nitrogen purging to enable analysis of sub-ppm metal concentrations. The cell was tested as a detector for metal complexes eluated from a modified gel permeation chromatographic column.

 

点击下载:  PDF (350KB)



返 回