首页   按字顺浏览 期刊浏览 卷期浏览 Kelvin and Caratheodory—A Reconciliation
Kelvin and Caratheodory—A Reconciliation

 

作者: Mark W. Zemansky,  

 

期刊: American Journal of Physics  (AIP Available online 1966)
卷期: Volume 34, issue 10  

页码: 914-920

 

ISSN:0002-9505

 

年代: 1966

 

DOI:10.1119/1.1972279

 

出版商: American Association of Physics Teachers

 

数据来源: AIP

 

摘要:

In conventional thermodynamics, the two most important consequences of the second law of thermodynamics, namely, the existence of an absolute temperature scale and the existence of an entropy function are deduced from the Kelvin-Planck statement or its equivalent, the Clausius statement, with the aid of the Carnot engine and Carnot refrigerator. In the Caratheodory method, a new statement of the second law is made; the Carnot cycle is dispensed with and purely analytical methods are used to derive the absolute temperature and the entropy. It is shown in this paper how the analytic methods of Caratheodory may be used without replacing the traditional statements of the second law by a new axiom. Both the Caratheodory statement of the second law and the Caratheodory theorem on Pfaffian differential forms are unnecessary.

 

点击下载:  PDF (923KB)



返 回