On the Problem of the Derivation of Spectroscopic Information from Structureless Electronic Spectra of Complex Molecules
作者:
S. Rashev,
期刊:
Spectroscopy Letters
(Taylor Available online 1985)
卷期:
Volume 18,
issue 3
页码: 179-187
ISSN:0038-7010
年代: 1985
DOI:10.1080/00387018508062222
出版商: Taylor & Francis Group
关键词: Electronic spectrum;Optically active vibration;Vibrational progression;Central moments
数据来源: Taylor
摘要:
The problem of obtaining spectroscopic information from structureless electronic (luminescence or absorption) spectra of complex molecules is treated. Our previous model for the description of structureless spectral bands is extended to account for two (rather than one) optically active vibrations in the electronic tarnsition. In comparison with previous treatments more detailed data are obtained a bout the changes in the excited state geometry as well as the frequencies of zero-electronic transitions for a number of (substituted) phtalymids.
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