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Dilatometric Study of the Kinetics of the Polymerization of Pure meta-and Pure para-Divinylbenzenes

 

作者: RichardH. Wiley,   Jung-Il Jin,   Tae-Oan Ahn,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1969)
卷期: Volume 3, issue 8  

页码: 1543-1550

 

ISSN:0022-233X

 

年代: 1969

 

DOI:10.1080/10601326908051951

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A comparison of the dilatometrically determined rates of polymerization of pure meta-and pure para-divinylbenzenes confirms the previous observation that the meta isomer polymerizes more rapidly than the para isomer. This difference shows up also in the initiator square root rate dependencies, the gel times, and the conversions at gel point. The effect of added regulator (carbon tetrabromide) on the polymerization of the meta isomer is to decrease the gel time and conversion at gel time.

 

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