Laser Raman spectroscopy of biomolecules. X‐frequency and intensity of the phosphodiester stretching vibrations of cyclic nucleotides
作者:
G. Forrest,
R. C. Lord,
期刊:
Journal of Raman Spectroscopy
(WILEY Available online 1977)
卷期:
Volume 6,
issue 1
页码: 32-37
ISSN:0377-0486
年代: 1977
DOI:10.1002/jrs.1250060108
出版商: John Wiley&Sons, Ltd.
数据来源: WILEY
摘要:
AbstractPhosphate frequencies for eight nucleoside 3′,5′‐ and four nucleoside 2′, 3′‐cyclic monophosphates have been determined by Raman and infrared spectroscopy based on comparisons with modified cyclic nucleotides and model cyclic phosphates. To a first approximation the symmetric diester stretching frequency, νs(OPO), is determined by the OPO bond angle. However, substitution on the phosphate ring also affects the frequency and intensity of νs(OPO). These results are discussed in terms of the use of νs(OPO) to determine the degree of backbone order in p
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