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Lanthanide Shift Reagents in Nuclear Magnetic Resonance Spectroscopy

 

作者: B. D. Flockhart,   J. Jonas,  

 

期刊: C R C Critical Reviews in Analytical Chemistry  (Taylor Available online 1976)
卷期: Volume 6, issue 1  

页码: 69-130

 

ISSN:0007-8980

 

年代: 1976

 

DOI:10.1080/10408347608542690

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Three decades have elapsed since the first detection of nuclear magnetic resonance (NMR) effects in bulk matter. The intervening period has been rich in rewarding results as the relevant theory has been thought through, the experimental techniques developed, and the applications accumulated. Nevertheless, a review of the current "state of the art" shows that significant progress continues to be made on almost all fronts. Within the last few years new fields of application have been opened by the development of super-conducting solenoids,1-3by the introduction of various spin-decoupling techniques,4,5and by the method of pulse Fourier transform NMR spectroscopy.6-9As these innovations originate mainly from progress in instrumentation, acquisition of the techniques by individual laboratories involves the expenditure of considerable sums of money. A much less expensive, but nonetheless important, development in NMR spectroscopy has been the recent introduction of paramagnetic lanthanide complexes as "chemical shift reagents." The theoretical background, practical aspects, and applications of these reagents form the subject of this review.

 

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