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Reactions of Menthone with Alkyl Amines and Amino Acids

 

作者: S. Watanabe,   T. Fujita,   M. Sakamoto,   E. Tsuruoka,  

 

期刊: Journal of Essential Oil Research  （Taylor Available online 1990）
卷期: Volume 2, issue 1  

页码: 25-31

 

ISSN:1041-2905

 

年代: 1990

 

DOI:10.1080/10412905.1990.9697812

 

出版商: Taylor & Francis Group

 

关键词: Menthone;Sodium cyanoborohydride;Menthone reduction;Alkylamino-p-menthane;3-p-Menthyl amino acid

 

数据来源: Taylor

 

摘要:

This paper concerns the reactions of menthone (I) with alkyl-amines and amino acids in the presence of sodium cyanoborohydride. The reaction of (I) with propylamine gave 3-propylamino-p-menthane (65% yield, cis/trans = 57:43). N-(2-Isopropyl-5-methylcylohexan-l-yl) glycine methyl-ester was obtained from (I) and glycine methylester.

 

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