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THE ELECTROLYSIS OF SOME ORGANIC COMPOUNDS WITH ALTERNATING CURRENT |
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Canadian Journal of Research,
Volume 17b,
Issue 5,
1939,
Page 147-158
J. W. Shipley,
M. T. Rogers,
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摘要:
The a-c. electrolysis of a number of organic compounds was carried out in order to ascertain what products might be obtained, what electrolytic conditions affected the nature and the yield of products, and to discover the general relations governing oxidation and reduction when a.c. is used. Oxidation was found to predominate over reduction, owing, probably, to the relatively low hydrogen overvoltage on the electrodes. The effect of varying the conditions of a-c. electrolysis was in general similar to that observed in d-c. electrolysis. Satisfactory yields were obtained only when a product of an irreversible process was concerned. A good yield of quinhydrone from the a-c. electrolysis of hydroquinone was secured at a relatively high current density. The chlorination of acetone by the a-c. electrolysis of a solution of acetic anhydride in hydrochloric acid gave a current yield of 35% at a current density of 2 amp. per cm2.
ISSN:1923-4287
DOI:10.1139/cjr39b-024
出版商:NRC Research Press
年代:1939
数据来源: NRC
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2. |
NOTE ON THE MOUNTING OF SMALL METAL SPECIMENS IN RESIN PLAQUES |
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Canadian Journal of Research,
Volume 17b,
Issue 5,
1939,
Page 159-159
C. Y. Hopkins,
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摘要:
not available
ISSN:1923-4287
DOI:10.1139/cjr39b-025
出版商:NRC Research Press
年代:1939
数据来源: NRC
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3. |
THE NITRATION OFm-DICHLOROAZOXYBENZENE AND THE REDUCTION OF SOME OF THE PRODUCTS |
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Canadian Journal of Research,
Volume 17b,
Issue 5,
1939,
Page 160-165
H. E. Bigelow,
W. H. Steeves,
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摘要:
The nitration ofm-dichloroazoxybenzene and the fractional crystallization of the nitrated products is described. Evidence for the structural formula of each is given. The reduction of some of the nitro derivatives with sodium arsenite to form azobisazoxy and trisazoxy compounds containing chlorine is also discussed.
ISSN:1923-4287
DOI:10.1139/cjr39b-026
出版商:NRC Research Press
年代:1939
数据来源: NRC
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