THE ALKALOIDS OF FUMARACEOUS PLANTS: III. A NEW ALKALOID, BICUCULLINE, AND ITS CONSTITUTION
作者:
Richard H. F. Manske,
期刊:
Canadian Journal of Research
(NRC Available online 1933)
卷期:
Volume 8,
issue 2
页码: 142-146
ISSN:1923-4287
年代: 1933
DOI:10.1139/cjr33-015
出版商: NRC Research Press
数据来源: NRC
摘要:
A base, now named bicuculline, previously isolated fromDicentra cucullariaand referred to as alkaloid α has been obtained fromCorydalis sempervirensandAdlumia fungosa. A chemical examination of this alkaloid has disclosed an exceptionally close relation to hydrastine, from which it differs only by the substitution of a methylenedioxy group for the two methoxyl groups. Accordingly, hydrolytic oxidation yields hydrastinine and 2-carboxy-3:4-methylenedioxy-benzaldehyde, which on reduction is converted into the known 3:4-methylenedioxy-phthalide.
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